Functionalized Carbon Nanotubes Produced by APCVD using Camphor

Document Type : Original Research Paper

Authors

Nanotechnology Reasearch Institute, University of Sistan and Baluchestan, Zahedan, I.R. Iran

Abstract

A simple chemical vapor deposition technique at atmospheric pressure (APCVD) is adopted to synthesize the aligned arrays of functionalized multi-walled carbon nanotubes (AMWCNTs) without using any carrier gas, at 230◦C, 750◦C and 850 ◦C. Camphor (C10H16O) is used as carbon source because this botanical hydrocarbon is chip and abundant which convert the CVD technique to a green method for production of carbon nanotubes (CNTs). The oxygen atoms in camphor oxidize the amorphous carbons and create hydroxyl functional groups in AMWCNTs. The molecular structure of camphor lead to form hexagonal and pentagonal carbon rings which increase the growth rate and alignment of MWCNTs. In this work, AMWCNTs are grown on silicon substrate, copper, and quartz. The synthesized AMWCNTs are characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) and transmission electron microscopy (TEM). The SEM results show that the deposited CNTs are formed in vertical aligned arrays and each has a functional OH group which is seen in FTIR spectroscopy results.

Keywords


[1] J. Bernholc, D. Brenner, M. Buongiorno Narde-lli, V. Meunier, C. Roland: Mechanical and Electrical Properties of Nanotubes, Annual Review of Materials Research 32 (2002) 347-375.
[2] V. Popov, Carbon nanotubes: properties and application, Materials Science and Engineering 43 (2004) 61–102.
[3] S. Iijima, Helical microtubules of graphitic carbon, Nature 354 (1991) 56.
[4] L. V. Radushkevich and V. M. Lukyanovich, Zh. Fizich. Khim: On the carbon streucture formed during thermal decomposition of carbon monoxide the presence of iron 26 (1952) 88.
[5] J.S. Speck, M. Endo, M.S. Dresselhaus: Structure and intercalation of thin benzeed carbon fibers, Journal of Crystal Growth (1989) 834-848.
[6] Zhifeng R, Yucheng L, Yang W: Properties and Applications of Aligned Carbon Nanotube Arrays, Springer-Verlag Berlin Heidelberg (2013) 183.
[7] Ando Y, Zhao X, Sugai T, Kumar: M. Materials Today 7 (2004) 22-29.
[8] Meyyappan M: Carbon Nanotubes Science and Applications, FL: CRC Press (2005) 237.
[9] Li G, Liao J.M, Hu G.Q, Ma N.Z, Wu P.J: Biosensors and Bioelectronics 20 (2005) 2140-2144
[10] Bethune D.S, Kiang C.H, de Vries M.S, Gorman G, Savoy R,Vazquez J , Beyers R: Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls, Nature (1993) 363-605.
[11] Eklund P C, Pradhan B K, Kim U J, Xiong Q, Fischer J E, Friedman A D, Holloway B C, Jordan K, Smith M W: Large-Scale Production of Single-Walled Carbon Nanotubes Using Ultrafast Pulses from a Free Electron Laser, Nano Lett 2 (2002) 561.
[12] Kumar M, Ando Y: Chemical Vapor Deposition of Carbon Nanotubes: A Review on Growth Mechanism and Mass Production (2010) 3739-3758.
[13] Kumar M, Ando Y: Diamond and Related Materials 12 (2003) 1845–1850.
[14] Mahanandia P, Vishwakarma P N, Nanda K K, Prasad V, Barai K, Mondal A K, Sarangi S, Dey G K Subramanyam: Solid State Communi  cations (2008) 143–148.
[15] Kumar M, Ando Y: A simple method of producing aligned carbon   nanotubes from an unconventional precursor – camphor, Chemical Physics Letters 374 (2003) 521–526.
[16] Kumar M, Ando Y: Single-wall and multi-wall carbon nanotubes from camphor—a botanical hydrocarbon, Diamond and Related Materials 12 (2003) 1845–1850.
[17] Charles B, Cher Ming T, Jeng C.K: FTIR spectroscopy as a tool for nano-material characterization, Infrared Physics & Technology 53 (2010) 434–438.